Coordinate covalent bond

A coordinate covalent bond, or dative bond, donor-acceptor is a covalent bond between an electron donor (ligand) and an acceptor. The donor must have at least one free electron pair and the acceptor at least one free orbital. The compound formed in this way is called complex.

Ligands[edit | edit source]

In general, these are compounds of elements with free eletron pairs, i.e. from the 15th, 16th and 17th group, or anions.

Halogens — (F₂) fluoro, (Cl₂) chloro, (Br₂) bromo, (I₂) iodo.
Anions — (SO₄^2-) sulfate, (ONO^-) nitrate, (NO₂^-) nitro, (NO₃^-) nitrie, (CN^-) cyano, (OCN^-) cyanato, (SCN^-) thiocyanato.
Neutral ligands — (H₂O) aqua, (NH₃) amine.

Acceptors[edit | edit source]

In general, these are metals with free d and f orbitals, especially if the orbital release is achieved by the formation of a cation, which can stabilize the bond to a negatively charged ligand, e.g. Cr³⁺, Cu²⁺, Fe²⁺, Fe³⁺, Co³⁺, Ni²⁺, but also from p-elements, e.g. B³⁺ a Al³⁺ used in organic syntheses as reducing agents ([AlH₄]^-, [BH₄]^-).

Isomerism of complex compounds[edit | edit source]

Isomerism of complex compounds can be divided into several groups: geometric, ionic, optical.

Stability of complex compounds[edit | edit source]

Most of the central atoms forming complex compounds in aqueous solution form aqua complexes, e.g. blue rock, where CuSO₄. 5 H₂O is only inconsistently written [Cu(H₂O)₄]SO₄. H₂O and upon the addition of a ligand that is more stable in the complex compound (most negatively charged or spatially stabilized ligands), the complex bound water is gradually replaced, and therefore the so-called consecutive stability constant is defined:

 $K_{k}={\frac {[A(H_{2}O)_{n-k}L_{k}]}{[A(H_{2}O)_{n-k+1}L_{k-1}]\cdot [L]}},$

kde A is the central atom, L is the ligand, n the coordination number of the central atom and k the number determining the consecutive constant (the number of bound ligands other than H₂O) and the total stability constant of the complex:

 $\beta _{n}=K_{1}\cdot K_{2}\cdot K_{3}\cdots K_{n}=\prod _{k=1}^{n}K_{k}$ .

In general, the stability of the complex is influenced by the properties of the central atom (increases with increasing of the charge and decreasing of the size), the properties of the ligand (number of binding sites, internal stress, ...) and their combination (some central atoms prefer specific ligands).

Color of complex compounds[edit | edit source]

The color of complex compounds is explained by the ligand field theory, which considers the energetic splitting of d orbitals in the electric field of ligands. The resulting energy differences between the originally degenerate d orbitals thus enable electron jumps and the absorption of light with a wavelength similar to visible light.

Links[edit | edit source]

References[edit | edit source]

GADE, Lutz H. Koordinationschemie. XVIII edition. Wiley-VCH, 1998. 562 pp. ISBN 3527295038.

VACÍK, Jiří. Obecná chemie. 1st edition. Praha : Státní pedagogické nakladatelství, 1986. 130 pp.

Chemická olympiáda. . Brožura chemické olympiády, kategorie A. 1st edition. 2007.

Wikipedia. Komplexní sloučenina [online]. ©2009. The last revision 18. 10. 2009, 14:37 (UTC), [cit. 18. 10. 2009]. <https://cs.wikipedia.org/w/index.php?title=Komplexn%C3%AD_slou%C4%8Denina&oldid=4551539>.